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Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T
Alternative TitleChin. J. Chem. Eng.
Li Jie1,2,3; Lin Xiao1,2; Ning Pengge1,2; Cao Hongbin1,2; Zhang Yi1,2; Crittenden, John C.4
2014
Source PublicationCHINESE JOURNAL OF CHEMICAL ENGINEERING
ISSN1004-9541
Volume22Issue:1Pages:89-97
AbstractThe primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of H2S in JM-T was measured at 298, 313, 333, 353, and 368 K with H2S partial pressures from 20 to 760 kPa and H2S loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.; The primary aliphatic amine Primene JM-T was investigated as a potential absorbent for H2S removal. The solubility of H2S in JM-T was measured at 298, 313, 333, 353, and 368 K with H2S partial pressures from 20 to 760 kPa and H2S loading from 0.02 to 0.8 mol H2S per mol JM-T. Relevant physical properties, such as density, viscosity and dielectric constant, of the material were measured. The thermodynamic model with two-suffix Margules equation was used to correlate the experimental vapor-liquid equilibrium data. Furthermore, the absorption mechanism in non-aqueous system is suggested and the difference between non-aqueous and aqueous absorption system is pointed out.
KeywordPrimene Jm-t H2s Removal Absorption Thermodynamic Model
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
DOI10.1016/S1004-9541(14)60016-1
URL查看原文
Indexed BySCI
Language英语
WOS KeywordEQUATION-OF-STATE ; AQUEOUS-SOLUTIONS ; N-METHYLDIETHANOLAMINE ; CARBON-DIOXIDE ; SELECTIVE ABSORPTION ; H2S SOLUBILITY ; CO2 ; PREDICTION ; MIXTURES ; GAS
WOS Research AreaEngineering
WOS SubjectEngineering, Chemical
WOS IDWOS:000329836500011
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Document Type期刊论文
Version出版稿
Identifierhttp://ir.ipe.ac.cn/handle/122111/8136
Collection研究所(批量导入)
Affiliation1.Chinese Acad Sci, Inst Proc Engn, Res Ctr Proc Pollut Control, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
4.Georgia Inst Technol, Brook Byers Inst Sustainable Syst, Atlanta, GA 30332 USA
Recommended Citation
GB/T 7714
Li Jie,Lin Xiao,Ning Pengge,et al. Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2014,22(1):89-97.
APA Li Jie,Lin Xiao,Ning Pengge,Cao Hongbin,Zhang Yi,&Crittenden, John C..(2014).Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T.CHINESE JOURNAL OF CHEMICAL ENGINEERING,22(1),89-97.
MLA Li Jie,et al."Measurement and Modeling for the Solubility of Hydrogen Sulfide in Primene JM-T".CHINESE JOURNAL OF CHEMICAL ENGINEERING 22.1(2014):89-97.
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