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| Thermal decomposition of ammonium perchlorate in the presence of Al(OH)(3)center dot Cr(OH)(3) nanoparticles | |
| Alternative Title | J. Hazard. Mater. |
| Zhang, WenJing1,2,3; Li, Ping1,2; Xu, HongBin1,2; Sun, Randi1,2; Qing, Penghui1,2; Zhang, Yi1,2 | |
| 2014-03-15 | |
| Source Publication | JOURNAL OF HAZARDOUS MATERIALS
 |
| ISSN | 0304-3894 |
| Volume | 268Issue:1Pages:273-280 |
| Abstract | An Al(OH)(3)center dot Cr(OH)(3) nanoparticle preparation procedure and its catalytic effect and mechanism on thermal decomposition of ammonium perchlorate (AP) were investigated using transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis and differential scanning calorimetry (TG-DSC), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis and mass spectroscopy (TG-MS). In the preparation procedure, TEM, SAED, and FT-IR showed that the Al(OH)(3)center dot Cr(OH)(3) particles were amorphous particles with dimensions in the nanometer size regime containing a large amount of surface hydroxyl under the controllable preparation conditions. When the Al(OH)(3)center dot Cr(OH)(3) nanoparticles were used as additives for the thermal decomposition of AP, the TG-DSC results showed that the addition of Al(OH)(3)center dot Cr(OH)(3) nanoparticles to AP remarkably decreased the onset temperature of AP decomposition from approximately 450 degrees C to 245 degrees C. The FT-IR, RS and XPS results confirmed that the surface hydroxyl content of the Al(OH)(3)center dot Cr(OH)(3) nanoparticles decreased from 67.94% to 63.65%, and Al(OH)(3)center dot Cr(OH)(3) nanoparticles were limitedly transformed from amorphous to crystalline after used as additives for the thermal decomposition of AP. Such behavior of Al(OH)(3)center dot Cr(OH)(3) nanoparticles promoted the oxidation of NH3 of AP to decompose to N2O first, as indicated by the TG-MS results, accelerating the AP thermal decomposition. (C) 2014 Elsevier B.V. All rights reserved.; An Al(OH)(3)center dot Cr(OH)(3) nanoparticle preparation procedure and its catalytic effect and mechanism on thermal decomposition of ammonium perchlorate (AP) were investigated using transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis and differential scanning calorimetry (TG-DSC), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis and mass spectroscopy (TG-MS). In the preparation procedure, TEM, SAED, and FT-IR showed that the Al(OH)(3)center dot Cr(OH)(3) particles were amorphous particles with dimensions in the nanometer size regime containing a large amount of surface hydroxyl under the controllable preparation conditions. When the Al(OH)(3)center dot Cr(OH)(3) nanoparticles were used as additives for the thermal decomposition of AP, the TG-DSC results showed that the addition of Al(OH)(3)center dot Cr(OH)(3) nanoparticles to AP remarkably decreased the onset temperature of AP decomposition from approximately 450 degrees C to 245 degrees C. The FT-IR, RS and XPS results confirmed that the surface hydroxyl content of the Al(OH)(3)center dot Cr(OH)(3) nanoparticles decreased from 67.94% to 63.65%, and Al(OH)(3)center dot Cr(OH)(3) nanoparticles were limitedly transformed from amorphous to crystalline after used as additives for the thermal decomposition of AP. Such behavior of Al(OH)(3)center dot Cr(OH)(3) nanoparticles promoted the oxidation of NH3 of AP to decompose to N2O first, as indicated by the TG-MS results, accelerating the AP thermal decomposition. (C) 2014 Elsevier B.V. All rights reserved. |
| Keyword | Al(Oh)(3)Center Dot Cr(Oh)(3) Nanoparticles Ammonium Perchlorate Thermal Decomposition Surface Hydroxyl Nano-effect |
| Subtype | Article |
| WOS Headings | Science & Technology ; Technology ; Life Sciences & Biomedicine |
| DOI | 10.1016/j.jhazmat.2014.01.016 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Keyword | CATALYTIC-ACTIVITY ; SURFACE OXYGEN ; FT-IR ; OXIDATION ; BAYERITE ; CHROMIA ; OXIDE ; PARTICLES ; MECHANISM ; GIBBSITE |
| WOS Research Area | Engineering ; Environmental Sciences & Ecology |
| WOS Subject | Engineering, Environmental ; Engineering, Civil ; Environmental Sciences |
| WOS ID | WOS:000333508500034 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Version | 出版稿 |
| Identifier | http://ir.ipe.ac.cn/handle/122111/8228 |
| Collection | 研究所（批量导入） |
| Affiliation | 1.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, WenJing,Li, Ping,Xu, HongBin,et al. Thermal decomposition of ammonium perchlorate in the presence of Al(OH)(3)center dot Cr(OH)(3) nanoparticles[J]. JOURNAL OF HAZARDOUS MATERIALS,2014,268(1):273-280. |
| APA | Zhang, WenJing,Li, Ping,Xu, HongBin,Sun, Randi,Qing, Penghui,&Zhang, Yi.(2014).Thermal decomposition of ammonium perchlorate in the presence of Al(OH)(3)center dot Cr(OH)(3) nanoparticles.JOURNAL OF HAZARDOUS MATERIALS,268(1),273-280. |
| MLA | Zhang, WenJing,et al."Thermal decomposition of ammonium perchlorate in the presence of Al(OH)(3)center dot Cr(OH)(3) nanoparticles".JOURNAL OF HAZARDOUS MATERIALS 268.1(2014):273-280. |
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| Thermal decompositio（1891KB） | 限制开放 | CC BY-NC-SA | Application Full Text | |||
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