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相转移催化元素硫的歧化反应
邓彤; 陈家镛
1987
Source Publication无机化学学报
Issue04Pages:128-131
Abstract本工作将相转移催化(PTC)应用于元素硫歧化反应,大大降低了反应温度,提高了反应速度。该反应被证实与熔态硫在水溶液中的歧化相同,即4S+6OH~-=2S~(2-)+S_2O_3~(2-)+3H_2O。比较了四乙基铵、四丁基铵、十六烷基三甲基铵和三辛基甲基铵四种相转移催化剂及四氯乙烯、二甲苯和四氯乙烷三种溶剂的影响。讨论了本体系相转移催化的证据。为改进以元素硫歧化反应为基础的提取冶金过程提供了依据。
Keyword相转移催化 元素硫 岐化季铵盐
Document Type期刊论文
Identifierhttp://ir.ipe.ac.cn/handle/122111/8711
Collection研究所(批量导入)
Recommended Citation
GB/T 7714
邓彤,陈家镛. 相转移催化元素硫的歧化反应[J]. 无机化学学报,1987(04):128-131.
APA 邓彤,&陈家镛.(1987).相转移催化元素硫的歧化反应.无机化学学报(04),128-131.
MLA 邓彤,et al."相转移催化元素硫的歧化反应".无机化学学报 .04(1987):128-131.
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